Jump directly to main navigation Jump directly to content Jump to sub navigation

Concentration measurement in liquids

Application examples

Concentration measurement explained

In the essential task of measuring concentration in liquids, the industry uses sophisticated products that guarantee the precision and efficiency of analytical processes. Understanding the exact composition of a solution (whether in pharmaceutical manufacturing, food technology or chemical processing) is made possible by advanced sensor technology that enables accurate concentration detection based on refractometric, potentiometric or spectroscopic principles.

These products, equipped with intelligent interfaces for data transmission and evaluation, offer the possibility of optimizing processes with low maintenance and a long service life, and thus represent an indispensable resource in quality control and process control.

The ultrasonic measuring method from LiquiSonic

The basis of the measuring method is a time measurement that can be realized very precisely and with long-term stability. The concentration or density of a liquid is calculated from the speed of sound. However, other parameters can also be determined, such as the Brix content, the solids content, the dry mass or the suspension density.

Our LiquiSonic® concentration and density meters are used in various processes for analyzing liquids.

In a typical case, a calibration curve is determined from the relationship between the speed of sound and the concentration. On this basis, the corresponding concentration is calculated from each measured sonic velocity value.

Our ultrasonic measuring devices have no mechanical parts that can wear out or age. They have outstanding advantages over competing measurement methods for determining concentration and density.

High reliability in determining the concentration of substances

The measuring method only requires precise time measurement to determine the concentration of the substance . The speed of sound is calculated from the sound propagation time and the known distance between the transmitter and receiver. The typical sensor design includes transmitter and receiver in a compact housing.

Thanks to the sensors, the measuring method is independent of the conductivity, color and transparency of the liquid and is characterized by a high degree of reliability in determining the substance concentration . The measuring accuracy of the devices is between 0.05 m% and 0.1 m%. In addition to sonic velocity measurement, all LiquiSonic® sensors have integrated temperature measurement for temperature compensation in the process.

Basics of concentration measurement

Determining the concentration of different liquids plays a key role in numerous procedures for different processes. The ratio of two substances to each other in a mixture or solution is measured and evaluated.

A central factor in this concentration measurement is the substance concentration. It is defined as the quantity of a substance per unit volume and is particularly important when analyzing solutions. It enables an exact assessment of the chemical composition and reactivity. This makes the concentration of substances an indispensable tool in many areas.

In addition, there are various measuring ranges that make it possible to measure the concentration of substances in different ways. They considerably expand the possibilities of concentration measurement and increase flexibility with regard to the specific requirements of the mixture or solution to be analyzed.

Finally, the amount of liquid to be analyzed plays an important role. It must be sufficient to enable accurate measurement, but not so large that it distorts the measurement result or unnecessarily complicates the measurement.

An important aspect of concentration measurement is the concentration of substances (molarity) in a solution, which is defined as the amount of a substance per unit volume. This is particularly relevant when analyzing a solution , where the molar concentration is crucial for assessing the chemical composition, concentrations and reactivity. Accurately measuring the concentration of a substance in a solution is critical to controlling processes, ensuring quality and conducting scientific research.

Applications of concentration measurements

Concentration measurement is one of the essential methods for analyzing the quality and safety-relevant characteristics of products and substances. It therefore plays a crucial role in several industries. There are various methods for measuring the concentration of a substance in a solution, depending on the type of substance and the requirements of the application.

A practical example of the use of concentration measurement can be found in the pharmaceutical industry, where the precise determination of the concentration of an active ingredient in drugs is essential to ensure their efficacy and safety. This shows the importance of precise measurement methods for determining the concentration of a substance quantity in quality assurance.

Examples for the measurement of a substance concentration

Concentration detection is used in the following areas, for example:

  • Chemistry/chemical production (for monitoring the composition of mixtures)

  • Pharmaceutical industry (e.g. for the production of medicines)

  • Food production (to control the product quality of food)

  • Metallurgy (to check the quality of metal ores)

  • Environmental analysis (to calculate pollutants in water)

In addition, concentration measurement is also commonly used in other areas, for example within industry and science.

Method for concentration measurement

The precise determination of the concentration of substances in liquids is of crucial importance for numerous scientific, industrial and medical applications. Different concentration measurement methods are used to quantify the exact content of a substance in a specific volume of liquid

These methods range from spectrophotometric techniques to chromatographic analyses and electrochemical measurements. The selection of the appropriate method depends on the properties of the substance to be analyzed, the requirements of the respective application and the available resources. There are various methods for measuring the concentration of solutions. Each of these measuring methods for determining the concentration of substances has its own advantages and disadvantages.

Refractiometry

The refractometer determines the refractive index of solutions and solids to measure the concentration. The determination of the refractive index is based on the refraction of light that is reflected or refracted by a liquid. Depending on the type and concentration of the dissolved substances, the light is refracted differently.

Consequently, the refractive index results from the concentration of the dissolved substances. An optical sensor (window) measures the reflection of a light beam that is reflected by an LED light source after it hits the sample. The refractometry method is extremely sensitive to influencing factors such as vibrations and requires extremely extensive and time-consuming calibration and regular maintenance.

Radiometry

Radiometry uses radioactive radiation to detect concentrations of a substance. A radioactive preparation sends its radiation through the measuring container, which is received by the detector. A scintillator converts the radioactive radiation into flashes of light and evaluates their number. As the penetration of the gamma rays depends on the substance, the density of the mass is determined from the intensity of the incoming radiation.

Gravimetry

Gravimetry measures the mass concentration by measuring the mass of a substance before and after a chemical reaction. It is used to determine the concentration of a specific element or compound in a sample. The basic process for determining the mass concentration of a substance involves the steps of precipitation, filtration and weighing. This process is extremely time consuming and typically requires large samples . In addition, the measurement principle is very prone to errors as it requires several manual process steps when defining the concentration of the substance.

Titration

Concentration measurement by titration is carried out by adding a solution with a known concentration value to a solution with an unknown concentration value until a chemical reaction occurs. This method is only suitable for certain solutions and is prone to errors when calculating the mass concentration due to manual handling.

Spectrophotometry for concentration measurement

In spectrophotometry, the volume of the sample plays a decisive role in determining the volume concentration of a substance quantity. The volume concentration is a unit of measurement for the quantity of a substance in a mixture in relation to the total volume of the mixture. It indicates what proportion of the total volume of a mixture consists of a particular substance.

Light absorption, which is a key measurement in this method, can be significantly influenced by the volume of the sample. Therefore, accurate determination and control of the sample volume is essential for precise measurement results. Spectrophotometry is suitable for a wide range of samples, including liquids, gases and solid materials.

This method of measuring particle volumes is highly susceptible to interfering factors that affect the accuracy of the sample.

Chromatography (such as HPLC, GC)

Chromatography separates components of a mixture based on their interactions with a stationary and a mobile phase.

There are also other measurement methods/processes that can be used to measure concentrations in certain scenarios. These include

  • Electrochemical methods (such as potentiometry, ion-selective electrodes)

  • pH measurement

  • NMR spectroscopy

  • Mass spectrometry

Selection criteria for concentration measurement methods

The selection of a suitable method for measuring concentration in liquids depends on several factors, including

  • Specificity of the application: The type of substances to be measured and the complexity of the solution.

  • Accuracy and sensitivity: Required precision and ability to detect minimum concentrations .

  • Speed and throughput: Need for fast measurement results and ability to handle large sample volumes.

  • Cost-effectiveness: Acquisition and operating costs of equipment and maintenance requirements.

  • Ease of use: Ease of operation and maintenance, especially in environments with few specialized personnel.

Density and speed of sound of some liquids

LiquidChemical formulaT [°C]
ρ [kg/dm3]
v [m/s]
AcetalCH3CH(OC2H5)2241,031378
Acetic acid ethyl esterCHCO.CHCOOH2H5251,0211417
AcetoneCH3CO.CH3200,79921192
Diethyl ester of acetonedicarboxylic acidC.(CH2COOC2H5)2221,0851348
 
AcetonitrileCH3CN200,7831304
AcetonylacetoneC6H10O2200,9711416
AcetophenoneC6H5.CO.CH3201,0261496
AcetylacetoneC5H8O2200,971383
Acetyl chlorideC2H3OCl201,1031060
Acetylene dichloride (cis)CHCl = CHCl251,2621025
Acetylene tetrabromideCHBr2.CHBr2202,9631041
Acetylene tetrachlorideCHCl2.CHCl2281,5781155
AcroleinC3H4O200,8411207
 CH2.CH2.COOC2H5221,0131376
Diethyl ester of adipic acid|
 CH°2CH2.COOC2H5
 CH2CH2COOCH3221,0671469
Dimethyl ester of adipic acid|
 CH2CH2COOCH3
Ammonium nitrate 10%NH4NO320 1540
Allyl chlorideCH2CH . CH2CCl280,9371088
Formic acidHCOOH201,2121287
Isoamyl etherC5H11OC5H11260,7741153
Amyl alcohol (n)C5H11OH200,8161294
Amyl alcohol (tert.)(CH3)2C(OH)C2H5280,8091204
Amyl acetateCH3COOC5H11260,8751168
Amyl bromide (n)C5H11Br201,223981
Amyl formateHCOOC5H11260,8691201
AnilineC6H5NH2201,0221656
Ascorbic acid 30%C6H8O620 1578
Barium sulfide 120 g/lBaS50 1591
BenzaldehydeC7H6O201,0461479
BenzeneC6H6200,8781326
Benzoyl chlorideC6H5COOCl281,2111318
BenzylacetoneC10H12O200,9891514
Benzyl alcoholC7H7OH201,0451540
Benzyl chlorideC7H7Cl201,0981420
Diethyl ester of succinic acid(CH2-COOC2H5)2221,0391378
Boric acid 5%H3BO330 1520
Tartaric acidCOCH3COOH201,2671471
BromalC2HOBr3202,55966
Bromonaphthalene (a)C10H7Br201,4871372
BromoformCHBr3202,89928
Butyric acidC3H7COOH200,9591203
Butyl alcohol (n)C4H9OH200,811268
Isobutyl alcohol (iso)(CH3)2CHCH2OH200,8021222
Tertiary butyl alcohol (tert.)C4H10O200,7891155
Butyl acetate (n)CH3COOC4H9260,8711271
Butyl bromide (n)CH3(CH2)2CH2Br201,275990
Butyl chloride (n)C4H9Cl200,8841133
2,3-ButanediolC4H10O2251,0191484
Butyl formateHCOOC4H9240,9061199
Butyl iodide (n)CH3(CH2)2CH2J201,614977
Butyllithium 20 1390
CaprolactamC6H11NO120 1330
Caproic acidC5H11COOH200,9291280
Caprylic acidC7H15COOH200,911331
CarvacrolC10H14O200,9761475
QuinaldineC10H9N201,0691575
QuinolineC9H7N201,0931600
ChlorobenzeneC6H5Cl201,1071291
Ethyl chloroacetateCH2ClCOOC2H5261,161234
Methyl chloroacetateCH2ClCOOCH3261,2321331
Alpha-chloronaphthaleneC10H7Cl20 1481
ChloroformCHCl3201,4891005
Ortho-chlorotolueneC7H7Cl201,0851344
Meta-chlorotolueneC7H7Cl201,071326
Para-chlorotolueneC7H7Cl201,0661316
CinnamaldehydeC9H8O251,1121554
CitralC10H16O200,8591442
CrotonaldehydeC4H6O200,8561344
CyclohexaneC6H12200,7791284
CyclohexanolC6H12O200,9621493
CyclohexanoneC6H10O200,9491449
CyclohexeneC6H10200,8111305
CyclohexylamineC6H13N200,8961435
Cyclohexyl chlorideC6H11Cl200,9371319
CyclopentadieneC5H6200,8051421
CyclopentanoneC5H#O240,9481474
1-DeceneC10H20200,7431250
Decyl alcohol (n)C10H21OH200,8291402
Decyl chloride (n)C10H21Cl200,8661318
Diacetosorbose 50% 50 1557
DiacetylC4H6O2250,991236
DiethylanilineC6H5N(C2H5)2200,9341482
Diethylene glycolC4H10O3251,1161586
Diethylene glycol etherC6H14O3250,9881458
Diethyl ketoneC2H5COOC2H5240,8131314
Dibromoethylene (cis)CHBr . CHBr202,246957
Dibromoethylene (trans)CHBr . CHBr202,231936
DichloroethaneC2H4Cl2201,2531034
Dichloroethylene (cis)CHCl CHCl201,2821090
Dichloroethylene (trans)CHCl CHCl201,2571031
Dichlorobenzene (m)C6H4Cl2281,2851232
Dichlorobenzene (o)C6H4Cl2201.3051295
Diethylene glycol diethyl etherO(CH2COOC2H5)2221,4331435
Dimethylamine, DMA 60%(CH3)2NH200,8261430
DimethylanilineC8H11N200,9561509
Dimethylacetamide 90%C4H9NO200,941550
Dimethylbenzoate    
Dimethylformamide, DMFC3H7NO200,948 
Dimethylglutaric acid C(CH3)2(COOC2H)2241,0381371
dimethyl ester
DioxaneC4H8O2201,0381389
DipenteneC10H16240,8641328
Diphenyl etherC6H5OC6H5241,0721469
DiphenylmethaneC6H5 - CH2 - C6H5281,0061501
Di-n-propyl etherC6H14O200,7471112
n-Dodecyl alcoholC12H25OH300,8271388
Iron(II) sulfateFeSO4201,9 
Elaidic acidC18H34O2450,8731346
Acetic acidCH3COOH201,0491150
Acetic anhydride(CH3CO)2O241,9751384
Ethyl etherC4H10O200,7141008
Ethyl alcoholC2H5OH200,7891180
Ethyl acetateCH3COOC2H5200,91176
Ethylene oxideC2H4O260,8921575
EthylbenzeneC6H5.C2H5200,8681338
EthylbenzylanilineC15H17N201,0291586
Ethyl bromideC2H5Br281,428892
Ethyl butyrateC3H. COOC2H5240,8771171
Ethyl caprylateCH3(CH2)6COOC2H5280,8721263
Ethylene bromideC2H4Br2202,0561009
Ethylene chlorideCH2Cl . CH2Cl231,2551240
Ethylene glycolC2H6O2201,1151616
EthyleneimineC2H5N240,83211395
Ethyl formate. COOC2H5241,1031721
Ethyl iodideC2H5J201,94869
Ethyl carbonateCO(OC2H5)2280,9771173
Ethyl phenyl ketoneC9H10O201,0091498
Ethyl phthalateC6H4(COOC2H5)2231,1211471
Ethyl propionateC2H5COOC2H5230,8841185
Hydrofluoric acidHF01,21362
Formaldehyde 60%CH2O851,1031516
FormamideCH3NO201,1391550
Furoic acidC4H4O4201,0511303
Furfuryl alcoholC5H6O2251,1351450
Geranyl acetateC12H20O2280,9151328
GlycerinC3H8O3201,2611923
HemellitolC9H12200,8871372
Heptane (n)C7H16200,6841162
HeptanoneC7H14O200,8141207
1-HepteneC7H14200,6991128
Heptyl alcohol (n)C7H15OH200,8231341
Hexamethylene- 201,2012060
diamine adipate
HexaneC6H14200,6541083
Hexyl alcohol (n)C6H13OH200,821322
Hexyl chloride (n)C6H13Cl200,8721221
Hexyl iodide (n)C6H13J201,4411081
HydrideC9H10200,911403
IndeneC9H8200,9981475
Isopropylbenzene (Cumene)C6H5CH(CH3)2200,8781342
IodobenzeneC6H5J201,831113
Jonone AC13H20O200,9321432
Carbolic acid (Phenol)C6H5OH201,0711520
Kerosene 200,811301
Cresol (o)C7H8O251,0461506
Cresol ethyl ether (o)C6H4(CH3)OC2H5250,9441315
Cresol methyl ether (m)C6H4CHOCH3260,9761385
Linseed oil 310,9221772
LinaloolC10H17OH200,8631341
Lithium bromideLiBr20 1612
Lithium chlorideLiCl202,068 
Maleic acidC4H4O201,0681352
Diethyl ester of malonic acidCH2(COOC2H5)2221,051386
MesityleneC6H3(CH3)2200,8631362
Mesityl oxideC6H10°O200,851310
Methyl ethyl ketoneC4H8O200,8051207
Methyl alcoholCH3OH200,7921123
Methyl acetateCH3COOCH3250,9281154
N-MethylanilineC7H9N200,9841586
Methyldiethanolamine, MDEAC5H13NO2201,041572
Methylene bromideCH2Br2242,453971
2-MethylbutanolC5H11OH300,8061225
Methylene chlorideCH2Cl201,3361092
Methylene iodideCH2J2243,233977
MethylenehexalinC6H10(CH3)OH220,9131528
Methylhexyl ketoneCH3COC6H13240,8171324
Methylisopropylbenzene (p)C6H4CH3CH(CH3)2280,8571308
Methylisobutylketone, MIBKC6H12O200,81220
Methyl iodideCH3J202,279834
Methyl propionateC2H5COOCH3240,9111215
Methyl silicone 20 1030
MethylcyclohexaneCH14200,7641247
Methylcyclohexanol (o)C7H14O260,9221421
Methylcyclohexanol (m)C7H14O260,9141406
Methylcyclohexanol (p)C7H14O260,921387
Methylcyclohexanone (o)C7H12O260,9241353
Methylcyclohexanone (p)C7H12O260,9131348
MonochloronaphthaleneC10H7Cl271,1891462
Monomethylamine, MMA 40%CH5N200,91765
MorpholineC4H9NO2511442
Sodium hydroxideNaOH201,432440
Sodium hypochloriteNaOCl201,221768
Sodium iodideNaJ50 1510
NicotineC10H14N2201,0091491
Nitroethyl alcoholNO2C2H4OH201,2961578
NitrobenzeneC6H5NO2201,2071473
NitromethaneCH3NO2201,1391346
Nitrotoluene (o)CH3C6H4NO2201,1631432
Nitrotoluene (m)CH3C6H4NO2201,1571489
NonaneC9H20200,7381248
1-NoneneC9H18200,7331218
Nonyl alcohol (n)C9H19OH200,8281391
Oleic acid (cis)C18H34O2450,8731333
Oenanthic acidC6H13COOH200,9221312
Octane (n)C8H18200,7031197
1-OcteneC8H16200,7181184
Octyl alcohol (n)C8H17OH200,8271358
Octyl bromide (n)C8H17Br201,1661182
Octyl chloride (n)C8H17Cl200,8721280
Olive oil 320,9041381
Diethyl oxalate(COOC2H5)2221,0751392
ParaldehydeC6H12O3200,9941204
PentaneC5H12200,6211008
PentachloroethaneC2HCl5201,6721113
1-PentadeceneC15H30200,781351
PerchloroethyleneC2Cl4201,6141066
Phenethyl ether (Phenetol)C6H5OC2H5260,7741153
PentaneC5H12200,6211008
Petroleum 340,8251295
Beta-phenyl alcoholC8H9OH301,0121512
PhenylhydrazineC6H8N2201,0981738
Phenyl methyl ether (Anisole)C6H5OCH3261,1381353
Beta-phenylpropyl alcoholC9H11OH300,9941523
Phenyl mustard oilC6H5NCS271,1311412
Picolin (a )C5H4NCH3280,9511453
Picolin (b )CH3C5H4N280,9521419
PinenC10H16240,7781247
PiperidineC5H11N200,861400
Phosphoric acid 50%H3PO4251,33341615
Polyvinyl acetate, PVAc 24 1458
n-propionitrileC2H5CN200,7871271
Propionic acidCH3CH2COOH200,9921176
Propyl alcohol (n)C3H7OH200,8041223
Propyl alcohol (i)C3H7OH200,7861170
Propyl acetateCH3COOC3H7260,8911182
Propyl chloride (n)C3H7Cl200,891091
Propylene glycolC3H8O2201,4321530
Propyl iodideC3H7J201,747929
Pseudobutyl-m-xyleneC12H18200,8681354
PseudocumolC9H12200,8761368
Phthalic anhydrideC6H4-(CO)2O201,527 
PyridineC6H5N200,9821445
MercuryHg2013,5951451
Resorcinol dimethyl etherC6H4(OCH3)2261,0541460
Resorcinol monomethyl etherC6H4OH OCH3261,1451629
SalicylaldehydeOH C6H4CHO271,1661474
Methyl salicylateOHC6H4COOCH3281,181408
Hydrochloric acid 35%HCl201,17381510
Carbon disulfideCS2201,2631158
Sulfuric acid 90%H2SO4201,8141455
Tetraethylene glycolC8H18O5251,1231586
TetrabromoethaneC2H2Br4202,9631041
TetrachloroethaneC2H4Cl201,61171
TetrachloroethyleneC2Cl4281,6231027
Carbon tetrachlorideCCl4201,595938
Tetrahydrofuran, THFC4H8O200,8891304
TetralinC10H12200,9671492
TetranitromethaneCN4O8201,6361039
Thiodiglycolic acid diethyl esterS(CH2COOC2H5)2221,1421449
     
Thioacetic acidC2H4OS201,0641168
ThiopheneC4H4S201,0651300
Toluidine (o)C7H9N200,9981634
Toluidine (m)C7H9N200,9891620
TolueneC7H8200,8661328
Transformer oil 320.8951425
Triethylene glycolC6H14O4251,1231608
TrichloroethyleneC2HCl3201,4771049
1,2,4-TrichlorobenzeneC6H3Cl3201,4561301
1-TrideceneC13H26200,7671313
Trimethylene bromideC3H6Br223,51,9771144
TrioleinC3H5(C18H33O2)3200,921482
1-UndeceneC11H22200,7521275
Valeric acidC4H9COOH200,9421244
Vinyl acetate, VAcC4H6O2200,9317900
WaterH2O250,9971497
Xylene (o)C8H10200,8711360
Xylene (m)C8H10200,8631340
Xylene (p)C8H10200,861330
Citronella oil 290,891076
Citric acid 60%C6H8O720 1686