The following three processes can be used for the separation of KCl from NaCl:
- Flotation
- Electrostatic separation
- Hot dissolution process
In flotation, KCl crystals treated with surfactants adhere to gas bubbles and are thus separated from sinking NaCl crystals. Through the robust LiquiSonic® Measurement technology the flotation can be monitored inline and the KCl concentration can be determined precisely.
LiquiSonic® Sound velocity measurement in a KCl suspension
Application
The pre-ground raw salt is mixed with saturated brine and finely sieved (crystal size ~ 1 mm). Optionally, sludge and clay are separated and the pre-cleaned suspension is stored. In the flotation cells, surfactants are used, which form a fine film exclusively on the KCl crystals. Introduced air bubbles bind the coated crystals. The KCl foam is mechanically separated from the surface. The non-binding NaCl crystals sediment and are in post-treatment.thickened and clarified.
The purified KCl suspension is finally dewatered by drying or centrifugation. Process water produced alongside the target product KCl is reused. LiquiSonic®offers robust concentration monitoring throughout the entire flotation, serving quality assurance and process optimization.
Installation
The LiquiSonic® Measurement technology is installed directly in the tank (storage, flotation) or in KCl-carrying pipelines. It is advisable to install from below for measurement in partially filled pipelines.
The LiquiSonic® Controller 30 can be connected to up to 4 sensors, allowing the flotation process to be monitored at multiple measuring points:
- Use of mother liquor
- Solution of the raw salt (sylvinite)
- Clarification
- Flotation unit
- KCl dewatering
Typical measuring range:
Concentration range: 1100 - 1600 g/l
Temperature range: 10 to 40 °C
Customer benefits
The inline measurement system LiquiSonic®ermöglicht mittels Schallgeschwindigkeit eine genaue Analyse der Prozesskonzentration. The robuste Sensorkonstruktion ohne bewegliche Teile und Nutzung von Sondermaterial (Titan) garantiert langfristig eine zuverlässige Prozessanalyse und -überwachung.
Further advantages for the user are:
- Optimal plant control through real-time information about the process state
- Increase of the flotation efficiency
- Detection of process disturbances in seconds
- Saving of material, maintenance, and energy
The extraction of sylvinite (a mixture of potassium chloride KCl and sodium chloride NaCl) plays a crucial role in the production of mineral fertilizers and high-purity salts for the chemical and pharmaceutical industries.
