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Density measurement in liquids

Density, defined as the measure of mass per volume, plays a pivotal role in the characterization of liquids. A density meter, far more than a mere device, serves as an essential tool for achieving precision across numerous fields. Its applications range from ensuring product quality and control in pharmaceutical manufacturing to aiding in the formulation of chemical compounds. This instrument, when integrated with an acoustic sensor sensitive to changes in a liquid's composition and fluid concentrations, transforms physical measurements—such as mass, volume, and sonic velocity—into valuable data. These data then inform and guide decisions in various industries.

Innovative approaches within this field incorporate principles like sound velocity, which reveals the speed at which sound waves travel through a liquid. This measurement is key to verifying the homogeneity and consistency of a sample. Through detailed analysis of such parameters, professionals can unravel the complex properties of liquids. This includes understanding their identity and behavior, which is crucial for predicting how they will act under different conditions and establishing standards in respective industries. By delving into these metrics, the density meter becomes not just a tool for measurement, but a beacon for innovation and quality in the development and application of liquids.

The ultrasonic measuring method from LiquiSonic®

The basis of the measuring method is a time measurement that can be realized very precisely and with long-term stability. The concentration or density of a liquid, indicative of product quality, is calculated from the speed of sound. However, other parameters can also be determined, such as the Brix content, the solids content, the dry mass or the suspension density.

Our ultrasonic measuring devices have no mechanical parts that can wear out or age. They have outstanding advantages over competing measurement methods for determining concentration and density.

The measuring method only requires precise time measurement. The speed of sound is calculated from the sound propagation time and the known distance between the transmitter and receiver. The typical sensor design includes transmitter and receiver in a compact housing.

The measuring method is independent of the conductivity, color and transparency of the liquid and is characterized by high reliability. The measuring accuracy of the devices is between 0.05 m% and 0.1 m%. In addition to the sonic velocity measurement, all LiquiSonic® sensors have an integrated measurement of the temperature in the process.

Our LiquiSonic® concentration and density meters are used in various processes for analyzing liquids.

In a typical case, a calibration curve is determined from the relationship or ratio between the speed of sound and the concentration. On this basis, the corresponding concentration is calculated from each measured sonic velocity value.

Basics of density measurement

Density measurements play an important role in one process or another. The mass of a certain substance in a volume is measured. The density is measured in kilograms per cubic meter (kg/m³)

The formula for a simple density measurement of two substances is ρ (Rho) is equal to mass m per unit volume V.

As a physical unit, density is influenced by the temperature and pressure of the substances. This is due to the fact that a change in temperature causes the substances to expand or contract. A change in temperature therefore has a significant effect on the accuracy of the data in the samples, which is why it is essential for modern sensors to also monitor this component.

Density can be used to draw conclusions about other chemical and physical properties of a material or substance. This makes measuring density an important point of reference for quality control, for example.

Density is defined for almost all materials. Due to the wide range of information available, density has become one of the most universal units that can be used in almost any process.

The accuracy of density determination can be significantly affected by various environmental influences. Temperature and pressure in particular play a decisive role, as they directly influence the physical states of a material. Temperature fluctuations can lead to expansion or contraction of the material to be measured, which in turn leads to changes in its density. A change in pressure also causes a change in density, particularly in the case of gases.

Modern density meters take these factors into account by applying temperature and pressure corrections in order to provide precise and reliable results.

Development of measuring devices for determining density

Modern density meters have seen significant technological progress, leading to enhanced precision, efficiency, and versatility.

Historic measurement tools, like basic hydrometers or mechanical balances, heavily depended on manual labor and visual estimations, making them less reliable in delivering precise measures of density.

Contemporary devices, however, incorporate progressive technologies such as ultrasonic sensors which gauge the speed of sound in a material, or digital pycnometers that calculate volume and mass with extreme accuracy. These instruments are capable of conducting automated, fast, and highly precise measurements, even under fluctuating environmental conditions.

Moreover, features like automatic temperature and pressure compensation help to reduce the impact of environmental changes on the measurement, thus assisting in determining the specific gravity with enhanced accuracy. These technical advancements in density meters provide a more reliable, efficient, and versatile user experience in contrast to their historical counterparts.

Comparison with other measurement methods

In comparison to alternative measurement techniques such as assessing viscosity, the use of a density meter presents universal application benefits, often proving to be both simpler and more cost-effective. Viscosity principally characterizes a liquid's flow characteristics, crucial in sectors where flow behavior and shear forces are significant, such as the food industry or lubricant manufacturing. In contrast, specific gravity as measured with a density meter is the preferred method when determining the exact composition or quality of a substance.

Density measurements provide a critical comparative advantage when analyzing substances in scenarios where traditional methods may fall short. For instance, within the realm of tight spaces, the applicability and accuracy of density-based assessments surpass those relying on the refractive index. While those measurements rely on the bending of light passing through fluids—requiring calibration and clear paths—the density measure utilizes a system that can operate effectively even in constrained environments. This adaptability makes density measurements an indispensable tool in various fields, including but not limited to chemical analysis and quality control processes. The precision afforded by density measurement tools ensures that professionals can rely on their readings, making it a preferred method for applications necessitating both strict precision and a high degree of reliability.

This is particularly relevant in the chemical and petrochemical industries, along with pharmaceutical manufacturing. Here, density meters, with their specific gravity sensors, provide invaluable information for substance identification, quality control, and monitoring of mixing processes. Even in ambient temperature conditions, a density meter remains a vital tool in areas demanding precise and reliable measurement results.

Applications of density data

Density measurement in liquids is an important process in many areas of application. For example, it plays an important role in the chemical and pharmaceutical industries, where the density of liquids is a decisive factor in the production of medicines and chemicals.

Density determination is also used in the food and beverage industry to ensure the quality and consistency of products such as wine, beer and milk.

In biology and medicine, the density of liquids is used to examine cell and tissue culture as well as sperm motility.

In addition, the density of liquids is continuously measured in the petrochemical and oil production industries to enable precise control of production processes. The diverse areas of application of density measurement in liquids illustrate its relevance and importance in various fields of industry and for different purposes.

Method for density measurement

There are various methods that are used to determine density. Each of these methods has its own advantages and limitations, which is why they are suitable for different applications.

In the precision measurement of densities in liquids, particularly in industrial applications, the accuracy of the measurement methods used is of critical importance. This is especially true in hazardous areas where the presence of flammable materials or vapors requires strict safety protocols. The ability to collect reliable data under such conditions is not only essential for safety in the workplace, but also contributes significantly to maintaining product quality. Accurate density determination allows operators to monitor and control critical process parameters, increasing the efficiency of operations while minimizing the risk of material loss and potentially hazardous situations.

Hydrometric method of measuring density

This traditional method uses a hydrometer, a special measuring instrument that is immersed in the liquid to be measured. The principle is based on Archimedes' principle: the hydrometer sinks to different depths in the liquid depending on its density. The density can then be read directly from the scale of the hydrometer. This method is inexpensive and easy to use, but less accurate and prone to errors due to temperature fluctuations and human reading errors. It is not suitable for viscous liquids or solids and provides a qualitative rather than quantitative measurement.

Hydrostatic weighing method for determining density

In this method, an object is weighed in both air and a liquid. The density of the liquid is calculated by relating the buoyancy experienced by the object in the liquid to its weight in air. This method is accurate and reliable, but requires precise balances and is more time-consuming than other methods. It is particularly suitable for laboratory applications and for materials that require a high degree if accuracy in density measurement.

Radiological measurement of density

This method uses ionizing radiation, usually gamma or X-rays, to determine the density of a material. The radiation is sent through the material and a detector measures the attenuation of the radiation. The denser the material, the stronger the attenuation. This method is well suited for inhomogeneous or large objects and allows non-invasive measurement. However, it requires specialized personnel and strict safety measures due to the use of ionizing radiation.

Pycnometer method for measuring density

A pycnometer is a precisely manufactured vessel with a known volume. To determine the density, the pycnometer is first weighed empty and then filled with the sample. The difference between the weights divided by the volume of the pycnometer gives the density of the sample. This method is very accurate and is often used for liquids and fine powders, but is less suitable for large quantities or materials with high viscosity.

Gas pycnometer for determining the density

A gas pycnometer uses a gas (usually helium) to determine the density of solids. The sample is placed in a chamber and the volume of gas displacing the sample is measured. The density is calculated from this volume and the mass of the sample. This method is particularly useful for porous materials or powders and offers high accuracy. However, it is more complex and usually limited to laboratory applications.

Our LiquiSonic® concentration and density meters are used in various processes for the analysis of liquids.

In a typical case, a calibration curve is determined from the relationship between the speed of sound and the concentration. On this basis, the corresponding concentration is calculated from each measured sonic velocity value.

Density measurements with LiquiSonic®

LiquiSonic® systems are used in a variety of processes to determine the density of different substances inline and automatically.

More information

Density and speed of sound of some liquids

In the following table we have listed the density and speed of sound of various liquids that are typically measured and used.

Density and speed of sound of some liquids

LiquidChemical formulaT [°C]
ρ [kg/dm3]
v [m/s]
AcetalCH3CH(OC2H5)2241,031378
Acetoacetic esterCHCO.CHCOOH2H5251,0211417
AcetoneCH3CO.CH3200,79921192
Acetone dicarboxylic acidC.(CH2COOC2H5)2221,0851348
diethyl ester
AcetonitrileCH3CN200,7831304
AcetonylacetoneC6H10O2200,9711416
AcetophenoneC6H5.CO.CH3201,0261496
AcetylacetoneC5H8O2200,971383
AcetylchlorideC2H3OCl201,1031060
Acetylendichloride (cis)CHCl = CHCl251,2621025
AcetylentretrabromideCHBr2.CHBr2202,9631041
AcetylentetrachlorideCHCl2.CHCl2281,5781155
AcroleinC3H4O200,8411207
Adipic acid diethyl esterCH2.CH2.COOC2H5221,0131376
|
CH°2CH2.COOC2H5
Adipic acid dimethyl esterCH2CH2COOCH3221,0671469
|
CH2CH2COOCH3
Ammonium nitrate 10%NH4NO320 1540
Allyl chlorideCH2CH . CH2CCl280,9371088
Formic acidHCOOH201,2121287
Amylether (iso)C5H11OC5H11260,7741153
Amyl alcohol (n)C5H11OH200,8161294
Amyl alcohol (tert.)(CH3)2C(OH)C2H5280,8091204
Amyl acetateCH3COOC5H11260,8751168
Amyl bromide (n)C5H11Br201,223981
Amyl formateHCOOC5H11260,8691201
AnilineC6H5NH2201,0221656
Ascorbic acid 30%C6H8O620 1578
Barium sulfide 120 g/lBaS50 1591
BenzaldehydeC7H6O201,0461479
BenzeneC6H6200,8781326
Benzoyl chlorideC6H5COOCl281,2111318
BenzylacetonC10H12O200,9891514
Benzyl alcoholC7H7OH201,0451540
Benzyl chlorideC7H7Cl201,0981420
Succinic acid diethyl ester(CH2-COOC2H5)2221,0391378
Boric acid 5%H3BO330 1520
Pyruvic acidCOCH3COOH201,2671471
BromalC2HOBr3202,55966
Bromonaphthalene (a)C10H7Br201,4871372
BromoformCHBr3202,89928
Butanoic acidC3H7COOH200,9591203
Buthyl alcohol (n)C4H9OH200,811268
Butyl alcohol (iso)(CH3)2CHCH2OH200,8021222
Butyl alcohol (tert)C4H10O200,7891155
Butyl acetate (n)CH3COOC4H9260,8711271
Butyl bromide (n)CH3(CH2)2CH2Br201,275990
Butyl chloride (n)C4H9Cl200,8841133
2,3 Butylene glycolC4H10O2251,0191484
Butyl formateHCOOC4H9240,9061199
Butyl iodide (n)CH3(CH2)2CH2J201,614977
Butyllithium 20 1390
CaprolactamC6H11NO120 1330
Caproic acidC5H11COOH200,9291280
Caprylic acidC7H15COOH200,911331
CarvacrolC10H14O200,9761475
ChinaldinC10H9N201,0691575
QuinolineC9H7N201,0931600
ChlorobenzeneC6H5Cl201,1071291
Ethyl chloroacetateCH2ClCOOC2H5261,161234
Methyl chloroacetateCH2ClCOOCH3261,2321331
a-chloronaphthaleneC10H7Cl20 1481
ChloroformCHCl3201,4891005
o-ChlortolueneC7H7Cl201,0851344
m-ChlorotolueneC7H7Cl201,071326
p-ChlortolueneC7H7Cl201,0661316
CinnamaldehydeC9H8O251,1121554
CitralC10H16O200,8591442
CrotonaldehydeC4H6O200,8561344
CyclohexaneC6H12200,7791284
CyclohexanolC6H12O200,9621493
CyclohexanoneC6H10O200,9491449
CyclohexesC6H10200,8111305
CyclohexylamineC6H13N200,8961435
Cyclohexyl chlorideC6H11Cl200,9371319
CyclopentadieneC5H6200,8051421
CyclopentanoneC5H#O240,9481474
l-DecenC10H20200,7431250
Decyl alcohol (n)C10H21OH200,8291402
Decylcloride (n)C10H21Cl200,8661318
Diacetone sorbose 50% 50 1557
DiacetylC4H6O2250,991236
DiethylanilineC6H5N(C2H5)2200,9341482
Diethylene glycolC4H10O3251,1161586
Diethylene glycol ethyl etherC6H14O3250,9881458
Diethylene ketoneC2H5COOC2H5240,8131314
Dibromoethylene (cis)CHBr . CHBr202,246957
Dibromoethylene (trans)CHBr . CHBr202,231936
DichloroethaneC2H4Cl2201,2531034
Dichloroethylene (cis)CHCl CHCl201,2821090
Dichloroethylene (trans)CHCl CHCl201,2571031
Dichlorobenzene (m)C6H4Cl2281,2851232
Dichlorobenzene (o)C6H4Cl2201.3051295
Diglycolic acid diethyl esterO(CH2COOC2H5)2221,4331435
Dimethylamine, DMA 60%(CH3)2NH200,8261430
DimethylanilineC8H11N200,9561509
Dimethylacetamide 90%C4H9NO200,941550
Dimethyl benzoate    
Dimethylformamide, DMFC3H7NO200,948 
Dimethylglutaric acidC(CH3)2(COOC2H)2241,0381371
dimethyl ester
DioxaneC4H8O2201,0381389
DipentsC10H16240,8641328
Diphenyl etherC6H5OC6H5241,0721469
DiphenylmethaneC6H5 - CH2 - C6H5281,0061501
Di-n-propyl etherC6H14O200,7471112
n-dodecyl alcoholC12H25OH300,8271388
Iron(II) sulfateFeSO4201,9 
Elaidic acidC18H34O2450,8731346
Acetic acidCH3COOH201,0491150
Acetic anhydride(CH3CO)2O241,9751384
Ethyl etherC4H10O200,7141008
Ethyl alcoholC2H5OH200,7891180
Ethyl acetateCH3COOC2H5200,91176
Ethylene oxideC2H4O260,8921575
EthylbenzeneC6H5.C2H5200,8681338
EthylbenzylanilineC15H17N201,0291586
Ethyl bromideC2H5Br281,428892
Ethyl butyrateC3H. COOC2H5240,8771171
Ethyl caprylateCH3(CH2)6COOC2H5280,8721263
Ethylene bromideC2H4Br2202,0561009
Ethylene chlorideCH2Cl . CH2Cl231,2551240
Ethylene glycolC2H6O2201,1151616
EthylenimineC2H5N240,83211395
Ethyl formate. COOC2H5241,1031721
Ethyl iodideC2H5J201,94869
Ethyl carbonateCO(OC2H5)2280,9771173
EthylphenylketoneC9H10O201,0091498
Ethyl phthalateC6H4(COOC2H5)2231,1211471
Ethyl propionateC2H5COOC2H5230,8841185
Hydrogen fluorideHF01,21362
Formaldehyde 60%CH2O851,1031516
FormanidCH3NO201,1391550
Furmaric acidC4H4O4201,0511303
Furfural alcoholC5H6O2251,1351450
Geranyl acetateC12H20O2280,9151328
GlycerineC3H8O3201,2611923
HemellitholC9H12200,8871372
Heptane (n)C7H16200,6841162
HeptanoneC7H14O200,8141207
1-HepteneC7H14200,6991128
Heptyl alcohol (n)C7H15OH200,8231341
Hexamethylene 201,2012060
diaminadipinate
HexaneC6H14200,6541083
Hexyl alcohol (n)C6H13OH200,821322
Hexyl chloride (n)C6H13Cl200,8721221
Hexyl iodide (n)C6H13J201,4411081
HydrindenC9H10200,911403
IndenC9H8200,9981475
Isopropylbenzene (cumene)C6H5CH(CH3)2200,8781342
IodobenzeneC6H5J201,831113
Jonon AC13H20O200,9321432
Carbolic acidC6H5OH201,0711520
Kerosene 200,811301
Cresol (o)C7H8O251,0461506
Cresol ethyl ether (o)C6H4(CH3)OC2H5250,9441315
Cresol methyl ether (m)C6H4CHOCH3260,9761385
Linseed oil 310,9221772
LinaloolC10H17OH200,8631341
Lithium bromideLiBr20 1612
Lithium chlorideLiCl202,068 
Maleic acidC4H4O201,0681352
Malonic acid diethyl esterCH2(COOC2H5)2221,051386
MesityleneC6H3(CH3)2200,8631362
MesityloxideC6H10°O200,851310
Methyl ethyl ketoneC4H8O200,8051207
Methyl alcoholCH3OH200,7921123
Methyl acetateCH3COOCH3250,9281154
N-methylanilineC7H9N200,9841586
Methyldiethanolamine, MDEAC5H13NO2201,041572
Methylene bromideCH2Br2242,453971
2-MethylbutanolC5H11OH300,8061225
Methylene chlorideCH2Cl201,3361092
Methylene iodideCH2J2243,233977
MethylenehexalineC6H10(CH3)OH220,9131528
MethylhexylketoneCH3COC6H13240,8171324
Methylisopropylbenzene (p)C6H4CH3CH(CH3)2280,8571308
Methylisobutylketone, MIBKC6H12O200,81220
Methyl iodideCH3J202,279834
Methyl propionateC2H5COOCH3240,9111215
Methyl silicone 20 1030
MethylcyclohexaneCH14200,7641247
Methylcyclohexanol (o)C7H14O260,9221421
Methylcyclohexanol (m)C7H14O260,9141406
Methylcyclohexanol (p)C7H14O260,921387
Methylcyclohexa-none (o)C7H12O260,9241353
Methylcyclohexa-none (p)C7H12O260,9131348
MonochloronaphthaleneC10H7Cl271,1891462
Monomethylamine, MMA 40%CH5N200,91765
MorpholineC4H9NO2511442
Sodium hydroxideNaOH201,432440
Sodium hypochloriteNaOCl201,221768
Sodium iodideNaJ50 1510
NicotineC10H14N2201,0091491
Nitroethyl alcoholNO2C2H4OH201,2961578
NitrobenzeneC6H5NO2201,2071473
NitromethaneCH3NO2201,1391346
Nitrotoluene (o)CH3C6H4NO2201,1631432
Nitrololuene (m)CH3C6H4NO2201,1571489
NonanC9H20200,7381248
1-NoneneC9H18200,7331218
Nonyl alcohol (n)C9H19OH200,8281391
Oleic acid (cis)C18H34O2450,8731333
Oenanthic acidC6H13COOH200,9221312
Octane (n)C8H18200,7031197
1-OcteneC8H16200,7181184
Octyl alcohol (n)C8H17OH200,8271358
Octyl bromide (n)C8H17Br201,1661182
Octyl chloride (n)C8H17Cl200,8721280
Olive oil 320,9041381
Oxalic acid diethyl ester(COOC2H5)2221,0751392
ParaldehydeC6H12O3200,9941204
PentaneC5H12200,6211008
PentachloroethaneC2HCl5201,6721113
1-pentadeceneC15H30200,781351
PerchloroethyleneC2Cl4201,6141066
Penylethyl ether (phenetol)C6H5OC2H5260,7741153
PentaneC5H12200,6211008
Petroleum 340,8251295
b-phenyl alcoholC8H9OH301,0121512
PhenylhydrazineC6H8N2201,0981738
Phenyl methyl ether (anisole)C6H5OCH3261,1381353
b-Phenylpropyl alcoholC9H11OH300,9941523
Phenyl mustard oilC6H5NCS271,1311412
Picoline (a)C5H4NCH3280,9511453
Picoline (b)CH3C5H4N280,9521419
PineneC10H16240,7781247
PiperidineC5H11N200,861400
Phosphoric acid 50%H3PO4251,33341615
Polyvinyl acetate, PVAc 24 1458
n-propionitrileC2H5CN200,7871271
Propionic sowsCH3CH2COOH200,9921176
Propyl alcohol (n)C3H7OH200,8041223
Propyl alcohol (i)C3H7OH200,7861170
Propyl acetateCH3COOC3H7260,8911182
Propyl chloride (n)C3H7Cl200,891091
Propylene glycolC3H8O2201,4321530
Propyl iodideC3H7J201,747929
Pseudobutyl-m-xyleneC12H18200,8681354
PseudocumolC9H12200,8761368
Phthalic anhydrideC6H4-(CO)2O201,527 
PyridineC6H5N200,9821445
MercuryHg2013,5951451
Resorcinol dimethyl etherC6H4(OCH3)2261,0541460
Resorcinol monomethyl etherC6H4OH OCH3261,1451629
SalicylaldehydeOH C6H4CHO271,1661474
Methyl salicylic acid esterOHC6H4COOCH3281,181408
Hydrochloric acid 35%HCl201,17381510
Carbon disulphideCS2201,2631158
Sulphuric acid 90%H2SO4201,8141455
Tetraethylene glycolC8H18O5251,1231586
TetrabromoethaneC2H2Br4202,9631041
TetrachloroethaneC2H4Cl201,61171
TetrachloroethyleneC2Cl4281,6231027
Carbon tetrachlorideCCl4201,595938
Tetrahydrofuran, THFC4H8O200,8891304
TetralinC10H12200,9671492
TetranitromethaneCN4O8201,6361039
Thiodiglycolic acid
diethyl ester
S(CH2COOC2H5)2221,1421449
     
Thioacetic acidC2H4OS201,0641168
ThiopheneC4H4S201,0651300
Toluidine (o)C7H9N200,9981634
Toluidine (m)C7H9N200,9891620
TolueneC7H8200,8661328
Transformer oil 320.8951425
Triethylene glycolC6H14O4251,1231608
TrichloroethyleneC2HCl3201,4771049
1,2,4 TrichlorobenzeneC6H3Cl3201,4561301
1-TrideceneC13H26200,7671313
Trimethylene bromideC3H6Br223,51,9771144
TrioleinC3H5(C18H33O2)3200,921482
1-UndecenC11H22200,7521275
Valeric acidC4H9COOH200,9421244
Vinyl acetate, VAcC4H6O2200,9317900
WaterH2O250,9971497
Xylene (o)C8H10200,8711360
Xylene (m)C8H10200,8631340
Xylene (p)C8H10200,861330
Citronella oil 290,891076
Citric acid 60%C6H8O720 1686